1.

MgAl_(2)O_(4), is found in the Spinal structure in which O^(2-) ions consititute CCP lattice, Mg^(2+) ions occupy 1/8th of the Tetrahedral voids and Al^(3+) ions occupy 1.2 of the Octahedral voids. Find the total +ve charge contained in one unit cell

Answer»

`+7//4` electronic CHARGE
`+6` electronic charge
`+2` electronic charge
`+8` electronic charge

Solution :Total positive charge = Charge on `MG^(2+)` + Charge on `AL^(3+) = (1)/(8) xx 8 xx 2 + (1)/(2) xx 4 xx 3 = 8` electronic charge


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