1.

MnO_(4)^(-) ions are reduced in acidic condition to Mn^(2+) ions whereas they are reduced in neutral condition to MnO_(2). The oxidation of 25 mL of a solution X containing Fe^(2+) ions required in acidic condition, 20 mL of a solution Y containing MnO_(4)^(-) ions. What volume of solution Y would be required to oxidise 25 mL of solution X containing Fe^(2+) ions in neutral condition ?

Answer»

11.4 mL
12 mL
33.3 mL
35 mL

Solution :`MnO_(4)^(-)+5Fe^(2+)+8H^(+) to Mn^(2+)+5Fe^(3+)+4H_(2)O`
`(M_(1)V_(1))/(1)=(M_(2)V_(2))/(5)`
`(M_(1)xx20)/(1)=(M_(2)xx25)/(5)`
`M_(1)=(M_(2))/(4)`
Neutral MEDIUM
`MnO_(4)^(-)+3Fe^(2+) +4H^(+) to MnO_(2)+3Fe^(3+)+2H_(2)O`
`(M_(1)V_(1))/(1)=(M_(2)V_(2))/(3)`
`((M_(2))/(4))xxV_(1)=(M_(2)xx25)/(3)`
`V_(1)=33.3 mL`


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