1.

Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP : 1 atmospheric pressure, 0°C). Show that it is 22.4 litres

Answer»

For one mole of an ideal gas, we have

pV = RT

Hence, V = RT/p

But R = 8.31 J mol-1 K-1

T = 273 K

and p = 1 atmosphere = 1.013 x 105 Nm-2

Thus, V = {8.31 x 273}/{1.013 x 105

= 0.024 m3

= 0.0224 x 106 cm3

= 22400 ml  (1 cm3 = 1 ml)



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