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Molecular hydrides are classified as electron deficient, electron precise and electron rich compounds. Explain each type with two examples.

Answer»

Solution :Molecular HYDRIDES are classified according to the relative numbers of ELECTRONS and BONDS, in their lewis structure as follow.
(i) Electron deficient hydrides : In these hydrides there are less than eight electrons present arround the central atom.
Group-13 elements make these type of hydrides. e.g., `BH_3, AIH_3`, etc.
These hydrides are lewis acid in nature .
(ii) Electron PRECISE hydrides : In this type of hydrides central atom have eight electrons. Group-14 elements, give these type of hydrides e.g. `CH_4, SiH_4`
(iii) Electron rich hydrides : In these type of hydrides central atom have than 8 electron. Group - 15, 16 and 17 elements gave this type of hydrides. e.g., `NH_3 , H_2O , HF` , etc.


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