N_(2)O_(4) hArr 2NO_(2).At 300K N_(2)O_(4) at 6 atmosphere is heated to 600K where equilibrium is established witha total pressure of 16 atmospheres. What isK_(p) at 600K ?

N_(2)O_(4) hArr 2NO_(2).At 300K N_(2)O_(4) at 6 atmosphere is heated t

1.	N_(2)O_(4) hArr 2NO_(2).At 300K N_(2)O_(4) at 6 atmosphere is heated to 600K where equilibrium is established witha total pressure of 16 atmospheres. What isK_(p) at 600K ?
Answer» <P> Solution :`underset(1-alpha)(1)(N_(2)O_(4(g))) harr underset(2alpha)underset(0)(2NO_(2(g)))` Total no. of MOLES at equilibrium = `1+alpha` From ideal gas equation `underset("before equlibrium")((P_(1))/(n_(1)T_(1)))=underset("after equilibrium")((P_(2))/(n_(2)T_(2)))` `(6)/(1 xx 300)=(16)/((1+alpha)600), alpha=(1)/(3)` `IMPLIES K_(P)=(P^(2)NO_(2))/(PN_(2)O_(4))=8`