1.

Name one reaction in which water acts (i) as an oxidising agent and (ii) as a reducing agent.

Answer»

Solution :(i) Oxidising agent. Water oxidises a number of highly electropositive METALS whose ELECTRODE potential is less than -0.83 V liberating `H_(2)` gas. For examples, sodium with `E^(@)=-2.71` reduces `H_(2)O` to `H_(2)` gas
`underset("(Reductant)")(2na(s))+ underset("(Oxidant)")(2H_(2)O)(l) to 2Na^(+) (aq) + 2OH^(-)(aq)+ H_(2)(g)`
(ii) Reducing agent. Water reduces a number of electronegative elements whose electrode potential is higher than +1.23 V liberating either `O_(2)` or `O_(3)` gas. For EXAMPLE, FLUORINE with `E^(@)=+2.87 V ` oxididses `H_(2)O`to `O_(2)` gas
`underset("(Oxidant)")(2F_(2)(g)) + underset("(Reductant)")(2H_(2)O(l)) to O_(2)(g) + 4H^(+) (aq) + 4F^(-) (aq)`


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