1.

Nitric acid can be produced from NH_(3) in three step process I) 4NH_(3(g))+5O_(2(g))rarr4NO_((g))+6H_(2)O_((g)) II) 2NO_((g))+O_(2(g))rarr2NO_(2(g)) III) 3NO_(2(g))+H_(2)O_((l))rarr2HNO_(3(aq))+NO_((g)) % yield of I, II, III reaction are respectively 50%, 60%and 80%. Then how much volume of NH_(3(g)) at STP is required to produce 2.25 gm of HNO_(3).

Answer»


Solution :`4NH_(3)+5O_(2)rarr4NO+6H_(2)O,50%`
`100rarr50`
`2NO+O_(2)rarr2NO_(2),60%`
`50 rarr50xx(60)/(100)=30`
`3NO_(2)+H_(2)Orarr2HNO_(3)+NO,80%`
`30rarr20xx(80)/(100)=16`
100 moles `NH_(3)=16` moles `HNO_(3)`
`?larr (2.25)/(63)` moles
`V_(NH_(3))` at STP = `(2.25xx100)/(63xx16)xx22.4=5`


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