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Nitrobenzene on reduction with LiAlH4 give |
Answer» <html><body><p><strong>Answer:</strong></p><p>he <a href="https://interviewquestions.tuteehub.com/tag/reduction-621019" style="font-weight:bold;" target="_blank" title="Click to know more about REDUCTION">REDUCTION</a> of the nitro-group might procede through attack of hydride onto the nitrogen atom or <a href="https://interviewquestions.tuteehub.com/tag/electron-968715" style="font-weight:bold;" target="_blank" title="Click to know more about ELECTRON">ELECTRON</a> transfer onto the group with subsequent reaction of the anion with proton (the exact <a href="https://interviewquestions.tuteehub.com/tag/mechanism-15329" style="font-weight:bold;" target="_blank" title="Click to know more about MECHANISM">MECHANISM</a> depends on conditions and <a href="https://interviewquestions.tuteehub.com/tag/reagents-1178484" style="font-weight:bold;" target="_blank" title="Click to know more about REAGENTS">REAGENTS</a>). It can produce a wide amount of monomeric products, in <a href="https://interviewquestions.tuteehub.com/tag/particular-1147539" style="font-weight:bold;" target="_blank" title="Click to know more about PARTICULAR">PARTICULAR</a>: nitrosocompounds, hydroxilamines and amines. It is known, that amines can react with nitrosocompounds forming the N=N bond. It looks like the first step in the reaction is a nucleoplilic attack of the amine nitrogen onto nitroso nitrogene with subsequent elimination of water.</p><p><strong>Explanation:</strong></p><p></p></body></html> | |