On electrolysis an alcoholic solution of sodium chloride gives a sweet smelling liquid (A) which gives carbylamine reaction and condenses with acetone to form hypnotic . What is (A) ? Ginve reactions of its formation.

On electrolysis an alcoholic solution of sodium chloride gives a sweet

1.	On electrolysis an alcoholic solution of sodium chloride gives a sweet smelling liquid (A) which gives carbylamine reaction and condenses with acetone to form hypnotic . What is (A) ? Ginve reactions of its formation.
Answer» `NaCI hArr Na^(+) +CI^(-).` At anode `CI_(2)` is discharged and electrolytic solution contains NaOH on electrolysis `CI_(2)` oxidises alcohol to acetaldehyde which is chlorinated to chloral. Chloral on hydrolysis yields chloroform. `C_(2)H_(5)OHoverset(CI_(2))underset([O])(to) CH_(3)CHO overset(CI_(2))(to) C CI_(3)CHOoverset(NaOH)(to)` `underset((A))(CHCI_(3))+HCOONa`

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On electrolysis an alcoholic solution of sodium chloride gives a sweet smelling liquid (A) which gives carbylamine reaction and condenses with acetone to form hypnotic . What is (A) ? Ginve reactions of its formation.

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