1.

On the basis of thermochemical equations (1), (2) and (3), find out which of the algebraic relationships given in options (A) to (D) is correct. (1) C_("(graphite)") + O_(2(g)) to CO_(2(g)) , Delta_(r) H= x "kJ mol"^(-1) (2) C_("(graphite)") + (1)/(2) O_(2(g)) to CO_((g)) , Delta_(r ) H= y "kJ mol"^(-1) (3) CO_((g)) + (1)/(2) O_(2(g)) to CO_((g)) , Delta_(r) H= z "kJ mol"^(-1)

Answer»

`z= x+y`
`x=y-z`
`x=y+z`
`y=2x-z`

Solution :The algebraic relationships of the GIVEN reaction is equation (A) -equation (B) = equation ( C)
(a) `C_("(graphite)") + O_(2(g)) , Delta_(R) H= x "kJ MOL"^(-1)`
(b) `(C_("(graphite)") + (1)/(2) O_(2(g)) to CO_(2(g)) , Delta_(r) H = x "kJ mol"^(-1) )/(CO_((g)) + (1)/(2) O_(2(g)) to CO_(2(g)) , Delta_(r) H = z "kJ mol"^(-1) ) `
Hence, `x-y - z " or " x=y+z`


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