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One gram of an alloy of aluminium and magnesium when heated with excess of dil. `HCI` forms magnesium chloride, aluminium chloride and hydrogen. The evolved hydrogen collected over mercury at `0^(0)C` has a volume of `1.2` litre at `0.92 atm` pressure. Calculate the composition of the alloy. |
Answer» Correct Answer - `Al=0.546g,Mg=0.454g` `Al+3HClrarrAlCl_(3)+(3)/(2)H_(2)uarr` `1.5x+y=0.04925" "...(I)` `x` mole `1.5x " "x+27+yxx24=1` `Mg+2HClrarrMgCl_(2)+H_(2)uarr` `x xx9+yxx8=0.33" "...(II)` `y` mole `% Al =(x xx27)/(1)xx100=54.6%` `Mg=45.4%` |
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