1.

One litre of oxygen at NTP weighs 1.46 g. How many litres of oxygen are needed for the combustion of 21.0 g of Mg whose equivalent weight is 1/2 mole?

Answer»

SOLUTION :The volume occupied by 1 equivalent at NTP is equivalent volume.
`therefore` equivalent volume of oxygen `=` volume of 8.0 g of oxygen at NTP (eq. WT. of O = 8 )
`= ( 8)/( 1.46) = 5.48` litres. (1.46) g oxygen contains 1 L at NTP)
Given that the equivalent weight of `MG = (1)/(2)xx 24 = 12 ""`(wt. of 1 mole of Mg = 24 g)
Now, in the COMBUSTION,
equivalent of Mg = equivalent of oxygen.
`therefore ("weight of Mg")/("eq. weight of Mg")=("volume of oxygen at NTP")/("eq. volume of oxygen")`
`(21)/(12) = ("volume of oxygen")/(5.48)`
`therefore` volume of oxygen `=` 9.59 litres.


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