1.

One mole fo carbon dioxide was found to occupy a volume of 1.32 litre at 48^(@)C under a pressure of 16.4 atm. Calculate the pressure that would have been expected from (i) the ideal gas equation, (ii) van der Waal's equation (a = 3.59 atm "litre"^(2) mol^(-1), b = 4.27 xx 10^(-3) " litre " mol^(-1) and R = 0.0821 "litre" - atom K^(-1) mol^(-1))

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ANSWER :(i) 19.96 ATM (II) 18.64 atm


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