1.

One mole of PCI_(5) is heated in one litre closed container. If 0.6 mole of chlorine is found at equilibrium, calculate the value of equilibrium constant.

Answer»

Solution :`[PCl_(5)]_("initial")=(1 mol)/(1 DM^(3))`
`[Cl_(2)]_(EQ)=0.6 mol dm^(-3)`
`PCl_(5)harrPCl_(3)+Cl_(2)`
`[PCl_(3)]_(eq)=0.6 "mole" dm^(-3)`
`[PCl_(5)]_(eq)=0.4 "mole" dm^(-3)`
`therefore K_(C)=([PCl_(3)][Cl_(2)])/([PCl_(5)])=(0.6xx0.6)/(0.4)`
`K_(C)=0.9`


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