1.

One reactant X on ozonolysis gives 2-product. In which molecular weight =72 mu, in structure 16 C-H sigma bond, 7C-C sigma bond and 1pi bond is there.

Answer»

Solution :(i) Molecular weight `= 72 mu`, molecular formula is `C_(4)H_(8)O.(48+8+16 = 72)`
Ozonolysis product has C=O (28) and other is alkyl group C 44 molecular weight `C_(3)H_(8)`.
(ii) Isomers are formed, having molecular formula `C_(4)H_(8)O`, X product is formed on ozonolysis.
`underset((A) C_(4)H_(8)O)(CH_(3)CH_(2)CH_(2)CHO)` and `underset((B)C_(4)H_(8)O)(CH_(3)COCH_(2)CH_(3))`
(iii) Therefire, UNSATURATED hydrocarbon structure and name is as follows :
Structure of X :
`overset(7)(CH_(3))overset(6)(CH_(2))overset(5)(CH_(2))overset(4)(CH)=underset(CH_(3))underset(|)overset(3)(C)-overset(2)(CH_(2))overset(1)(CH_(3))overset(O_(3))rarr A+B`
Name (X) : 3-methyl-hept-3-ene
(iv) Structure : `C_(8)H_(16)`
There are 16 C-H `SIGMA` bond
`7 C -C sigma`-bond
`1C-C pi`-bond


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