1.

Ortho effect is special type of effect that is shown by o-subsituents .This ortho-effect operates at the benzoic acids irrespective of the polar type. Nearly all o-substituted benzoic acid are stronger than benzoic acid. Benzoic acid is a resonance stabilised and so the carboxyl group is coplaner with the ring. An o-subsituent tends to prevent this coplanarity. What is the order of K_(a) of following compounds ?

Answer»

`I gt II gt III gt IV gt V`
`II gt I gt III gt IV gt V`
`V gt VI gt III gt I gt II`
`III gt II gt I gt V gt IV`

ANSWER :A


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