1.

Out of H and H_(2) , the latter has higher first ionization energy while out of O and O_(2) , the former has higher first ionization energy . Explain why .

Answer»

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Solution :In `H_(2)` , FIRST electron has to be REMOVED from `sigma` (1s) which has lower energy (more stable ) than H-atom . In
`O_(2)` first electron has to be removed from `pi^(**) (2p_(x)) or pi^(**) (2p_(y))` ORBITALS which has HIGHER energy than 2 p -
orbital of O-atom .


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