1.

Oxidation of an alkene X gives a diol , further oxidation gives a diketone. Which one of the following could be X ?

Answer»

`(CH_3)_2C=C(CH_3)_2`
`CH_3CH=C(CH_3)_2`
`(CH_3)_2CHCH=CH_2`
`C_6H_5CH=CHC_6H_5`

SOLUTION :SINCE the diol on further oxidation forms a diketone , therefore, the diol must be monosubstituted, i.e., it must contain `2^@` alcoholic groups. Therefore, option (d) is correct.
`UNDERSET"(X)"(C_6H_5CH=CHC_6H_5)underset"(BAEYER's reagent)"overset("Cold. aq. ALK." KMnO_4) to underset(("Diol contains two " 2^@ "alcoholic groups"))(C_6H_5-underset(OH)underset|CH-underset(OH)underset|CH-C_6H_5)overset"[O]"to underset"Diketone"(C_6H_5-undersetundersetO(||)C-undersetundersetO(||)C-C_6H_5)`


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