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Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below : `(1)/(2)Cl_(2)(g)overset((1)/(2)Delta_(diss)H^(Theta))rarrCl(g)overset(Delta_(eg)H^(Theta))rarrCl^(-)(g)overset(Delta_(hyd)H^(Theta))rarrCl^(-)(aq)` The energy involved in the conversion of `(1)/(2)Cl_(2)(g) " to " Cl^(-)(aq)` (Using the data, `Delta_(diss)H_(Cl_(2))^(Theta)=240 kJ mol^(-1)`, `Delta_(eg)H_(Cl)^(Theta)=-349 kJ mol^(-1)`, `Delta_(hyd)H_(Cl)^(Theta)=-381 kJ mol^(-1))` will beA. `-610 kJ mol^(-1)`B. `-850 kJ mol^(-1)`C. `+120 kJ mol^(-1)`D. `+152 kJ mol^(-1)` |
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Answer» Correct Answer - A `DeltaH=(240)/(2)-349-381` `=120-349-381=-610kJ//mol`. |
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