Oxidizing power of chlorine in aqueous solution can be determined by the parameters indicatedbelow: (1)/(2)Cl_(2)overset((1)/(2) Delta_("disso")H^(c-))(rarr)Cl(g) overset(Delta_(cg) H^(c-))(rarr) Cl^(-)(g)overset(Delta_(hyd)H^(c-))(rarr) Cl^(-) (aq)The energy involved inthe conversion of (1)/(2)Cl_(2)(g) toCl^(-) (aq)( using the data,Delta_(disso) H_(Cl_(2))^(c-)= 240 kJmol^(-1),Delta_(eg)H = - 349 kJ mol^(-1) Delta_(hyd)H_(cl) ^(c-) = - 381kJ mol^(-1)) will be

Oxidizing power of chlorine in aqueous solution can be determined by t

1.	Oxidizing power of chlorine in aqueous solution can be determined by the parameters indicatedbelow: (1)/(2)Cl_(2)overset((1)/(2) Delta_("disso")H^(c-))(rarr)Cl(g) overset(Delta_(cg) H^(c-))(rarr) Cl^(-)(g)overset(Delta_(hyd)H^(c-))(rarr) Cl^(-) (aq)The energy involved inthe conversion of (1)/(2)Cl_(2)(g) toCl^(-) (aq)( using the data,Delta_(disso) H_(Cl_(2))^(c-)= 240 kJmol^(-1),Delta_(eg)H = - 349 kJ mol^(-1) Delta_(hyd)H_(cl) ^(c-) = - 381kJ mol^(-1)) will be
Answer» `- 850kJ MOL^(-1)` `+120kJ mol^(-1)` ` +152kJ mol^(-1)` `- 610 kJmol^(-1)` Solution :For the process `(1)/(2) Cl_(2)(G) rarr Cl^(-) (aq) `,using the given steps, `DeltaH =(1)/(2)Delta_(diss)H_(Cl_(2))+ Delta_(eg) Cl_+Delta_(hyd) H_(Cl^(-))` `= ( 240)/(2) - 349-381kJmol^(-1)` `=120 -730=-610 kJ mol^(-1)`