1.

P is an alcohol which onheating withAl_(2)O_(3)_(3) forms an alkene Q. Q on ozonolysis produces R and S. when the mixture of R andS is heated with conc. NaOH, redox reaction takes place and a mixture of an acid salt and alcohol is formed.The compound R and S are

Answer»

`CH_(3)-OVERSET(CH_(3))overset(|)(C)=O,CH_(2)=O`
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)=CH=O,CH_(3)CH=O`
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=O +CH_(2)=O`
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=O +CH_(2)=O`

SOLUTION :`P=CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-COCl+CH_(3)MgCl`
`,Q= CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=CH_(2) , ""R&S=CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=O,O+CH_(2)=O`


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