1.

PCl5 is possible but NCl5 does not exist :(a) in N, d-sub-shell is absent(b) ionization energy of N is very high(c) it does not like Cl(d) None of these

Answer»

(a) NCl5 in not possible because N does not contain d-orbitals. Only nitrogen has a tendency to form pπ –  pπ multiple bonds. Other forms dπ –pπ multiple bonds easily



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