1.

PCl5, PCl3 and Cl2 are at equilibrium at 500K and having concentration 1.59 M PCl3, 1.59 M Cl2 and 1.41 M PCl5. Calculate KC for the reaction, PCl5 ⇌ PCl3 + Cl2.

Answer»

For the reaction, PCl5 ⇌ PCl3 + Cl2

Equilibrium constant = Kc\(\frac{[PCl_3][Cl_2]}{[PCl_5]}\)

\(\frac{(1.59)\times(1.59)}{(1.41)}\)

= 1.79



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