1.

Periodicproperties show aregular gradation onmovingfrom leftto rightin aperiodor fromtoptobottomin a group . Downa groupthe atomicionicradii, metalliccharacterand reducing characterincreasewhileionizationenthalpyand electronegativitydecrease. Alonga periodfrom leftto rightatomic ionicradiiand metalliccharacterdecrease whileionizationenthalpyelectronegativitynon- metalliccharacterand oxidisingpowerincreases. However ,electrongainenthalpybecomesless negativedown agroupbut morenegativealonga period. Incontrastinertgaseshavepositiveelectrongainenthalpies whichdo not showanyregular trend .Amongst the followingelements(whoseelectronicconfigurationare givenbelow ) theone havingthe highestionizationenthalpy is :

Answer»

`[Ne] 3 s^(2)3p^(1)`
`[Ne] 3S^(2)3p^(3)`
`[Ne] 3s^(2)3p^(2)`
`[Ar] 3d^(10)4s^(2)4P^(3)`

Solution :Both (b) and ( d)havesimilarexactly HALF- filledelectronicconfigurationbut thesizeof ( b)is smallerthat that of ( d) .


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