1.

Periodicproperties show aregular gradation onmovingfrom leftto rightin aperiodor fromtoptobottomin a group . Downa groupthe atomicionicradii, metalliccharacterand reducing characterincreasewhileionizationenthalpyand electronegativitydecrease. Alonga periodfrom leftto rightatomic ionicradiiand metalliccharacterdecrease whileionizationenthalpyelectronegativitynon- metalliccharacterand oxidisingpowerincreases. However ,electrongainenthalpybecomesless negativedown agroupbut morenegativealonga period. Incontrastinertgaseshavepositiveelectrongainenthalpies whichdo not showanyregular trend .The incorrectstatementamong thefollowingis :

Answer»

The firstionizationpotentialof A1 islessthanthefirstionizationpotential of Mg.
The secondionizationpotential of Mg isgreaterthan thesecondionizationpotentialof NA .
The firstionizationpotentialof Na isless than the firstionizationpotentialof mg
Thethirdionizationpotentialof Mg isgreaterthan thethirdionizationpotentialof A1.

Solution :`Delta_(i)H_(2)` of Na ishigherthan THATOF Mg becausein CASEOF Na thesecondelectronhas toberemovedfrom thenoblegas corewhile in case ofMg, REMOVALOF secondelectrongivesa nobegas core.


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