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| 1. |
Phosphorus acid can act both as oxidising agent as well as reducing agent while phosphoric acid is only an oxidising agent. Explain. " " Or Phosphorus acid undergoes disproportionation reaction but phosphoric acid does not. Explain. |
| Answer» The behaviour is linked with the oxidation state of phosphorus atom in the two acids.In phosphorus acid `(H_(3)OPO_(3))`. the oxidation state of P is +3.It is in a position to increase its oxidation state (acts as redcuiing agent) as well as sdecrease it (acts as oxidising agent).The oxidation state of phosphorus in phosphoric acid `(H_(3)PO_(4))` is +5 .Since it cannot increase it vbeyond 5, it cannot act as reducing agent .Hower it can behave as oxidising agent bty decreasing its oxidation state. | |