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Positive deviation from ideal behaviour takes place because ofA. molecular interaction between atoms and `(PV)/(nRT) gt1` .B. molecular interaction between atoms and `(PV)/(nRT) gt1` .C. finite size of atoms and `(PV)/(nRT) gt1`D. finite size of atoms and `(PV)/(nRT) gt1` |
Answer» For positive deviations `Z gt1` the condition when repulsive forces predominates Also at high `P,V` is small and b cannot be ignored but the factor `(a)/(V^(2))` can be neglected in comparison to `P` Thus `Z =1 +(Pb)/(RT)` . | |