1.

Potassium metal is a better reducing agent that sodium but still potassium metal can be obtained by reduction of potassium chloride with sodium . How does it happen ?

Answer»

Solution :Potassium can be OBTAINED by reduction of KCl and Na vapours at 1125 K in a large fractionating column .
`KCl +Na overset(1125K)(to) NaCl + K`
This reduction occurs because the lattice energy of NaCl is higher `(-770 kJ mol^(-1))`than that of KCl `(-703 kJ mol^(-1)`) .


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