1.

Predict which out of the following molecules will have higher diple moment and why ? CS_(2) and OCS

Answer»

Solution :`Soverset(larr)=Coverset(rarr)(=S)and Ooverset(larr)=Coverset(rarr)(=S)` , bond are linear MOLECULES but bond moments in `CS_(2)` cancel out so that NET
dipole MOMENT = 0 . But in OCS, bond MOMENTOF C = O is not equal to that of C = S . Hence , it has a net
dipole moment. THUS , dipole moment of OCS is higher.


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