1.

Primary alcohol can easily be prepared from primary alky `1` halide `via S_(N)2`reaction with aqueous `NaOH`. However, similar method does not work for the perparation tertiary acholo (tertiary butanol) from tertiary buty`1` bromide except?A. `(CH_(3))_(3)CBr+CH_(3)COOAg(aq)rarroverset(H_(3)O^(+))to`B. `(CH_(3))_(3)CBr+KOHoverset(C_(2)H_(5)OH)rarrunderset(Heat)overset(H_(2)SO_(4))rarr`C. `(CH_(3))_(3)CBr underset((C_(2)H_(5))_(2)O)overset(Mg)rarr underset((iii)H_(3)O^(+))overset((i)O^(2))rarr`D. `(CH_(3))_(3)CBr overset(KOH//Ethanol)rarr underset((ii)H_(2)O_(2)//NaOH)overset((i)B_(2)H_(6))rarr`

Answer» Correct Answer - A
`3^(@)R^(X)`undergoes elimination with base.
`(CH_(3))_(3)CBr+CH_(3)COOAg(aq)rarr`
`CH_(3)-overset(O)overset(||)C-underset((Ester))O-C(CH_(3))_(3)overset(H_(3)O^(+))rarr`
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OH-CH_(3)COOH`


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