1.

'Rate of Melting = Rate of freezing'' When is the above condition achieved ? Explain with an example.

Answer»

Solution :Let US consider the melting of ICE in a closed container at 273 K. In the PROCESS the total number of WATER molecules leaving from and returning to the solid phase at any instant are equal.
If some ice-cubes and water are placed in a thermos flask (at 273 K and 1 at, pressure). then there will be no change in the mass of ice and water.
At equilibrium,
`{:("Rate of meltingRate of FREEZING"),("="),("of iceof water"),(""H_(2)O(S)hArrH_(2)O(l)):}`
The temperature at which the solid and liquid phases of a substance are at equilibrium is called the melting point or freezing point of that substance.


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