1.

Reaction between nitrogen and oxygen takes place as follows : 2 N_(2) (g) + O_(2) (g) hArr 2 N_(2) O (g) If a mixture of 0*482 mol of N_(2) and 0*933 mol of O_(2) is placed in a reaction vessel of volume 10 L and allowed to form N_(2)Oat a temperature for which K_(c) = 2*0 xx 10^(-37) . Determine the composition of the equilibrium mixture.

Answer»

Solution :` {:(,2 N_(2) (g) ,+,O_(2)(g),hArr,2 N_(2)O(g)),("Intial",0*482 "mol",,0*933"mol",,),("At eqm.",0*482 "mol",,0.933-x//2,,x),("Molar conc." ,(0*482-x)/10,,(0*933-x//2)/10,,x/10):}`,
As K ` = 2*0xx 10 ^(-37)` is very small , this means that the amount of `N_(2) and O_(2) ` reacted (x)is very very small . Hence , at equilibrium , we have `[N_(2)] = 0* 0482 "mol"L^(-1), [O_(2)] = 0* 0933 "mol" L^(-1) , [N_(2)O]= 0*1x `
` :. K_(c) = (0*1 x)^(2) /((0*0482)^(2) (0*0933)) = 2* 0 xx 10^(-37) ` (GIVEN)
On solving, this GIVES `x = 6*6XX 10^(20)`
`:. [N_(2)O ] = 0*1x 6*6xx 10^(-21)"mol"L^(-1)`


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