1.

Saline hydrides are known to react with water violently poducing fire. Can CO_(2) , a well known fire entingiusher, be used in this case? Explain .

Answer»

Solution :Saline hydrides (such as NaH, `CaH_(2)`, etc.) , react with water violently to form the corresponding metal hydroides with the evolution of dihyrogen .
(`NaH(s) + H_(2)O(l) to NaOH(aq) + H_(2)(g)`
`CaH_(2)(s) + 2H_(2)O(l) to Ca(OH)_(2) (aq) +2H_(2)(g)`
These REACTIONS are so much exothermic that the evolved `H_(2)` catches fire. The fire so produced cannot be extinguished by`CO_(2)` because it gets reduced by the HOT metal hydride to form sodiym FORMATE.
`NaH+ CO_(2) to HCOONa`
`However, sand is useful since it is a highly STABLE solid


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