1.

Select from eachgroupthe specieswhichhas thesmallestradius statingappropriate reason (a) O, O^(-) , O^(2-)(b) K^(+), Sr^(2+) , Ar ( C) Si, P,Cl

Answer»


Solution :(a) Amongthe differentspeciesof the sameatomthe sizeincreases as themagnitude tonegativecharge increase : Thereforeamong `O, O^(-)` and `O^(2-), O` hasthe smallestradius.
(b)Although `Sr^(2+)` has Kr gasconfiguration(i.e., has four shells ) but `K^(+)` has Ar gasconfiguration (i.e., has three shells), nevertheless IONIC sizeof `Sr^(2+)` is smallerthan thatof `K^(+)` obviously due tohigher nuclear charge whichoutweighsthe effect of anadditional shell.
( c) Si P and CI and belongto 3RD period.Sinceatomicsize decrease as thenuclear chargeincrease ThereforeCI withthe HIGHEST nuclear charge hs the smallest radius.


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