1.

Select incorrect match for the following complexes.

Answer»

`[IrF_(6)]^(3-)""(DeltagtP)`
`[Co(H_(2)O)_(6)]^(3+)""(DeltaltP)`
`Fe(CO)_(5)""(DeltagtP)`
`[PdCl_(2)(SCN)_(2)]^(2-)""(DeltagtP)`

Solution :(A) Due to highof `Z_(eff)" in "Ir^(+3)`, which belongs to `III^(rd)` transition series `(PltDelta_(0))`
(B) Due to HIGHER oxidation STATE of Cobalt in `[overset(III)(Co)(H_(2)O)_(6)]^(3+),PltDelta_(0)`,also `H_(2)O` lies to'wards stronger ligand sife in spectrochemical series.
(C) CO is a STRONG field ligand hence `PltDelta`
(D) Due to high value `Z_(eff)` of `Pd^(2+)`, which belongs to `2^(nd)` transition series, `(PltDelta)""]`


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