1.

Select the members of group 14 that (i) forms the most acidicdioxide (ii) is commonly found in +2 oxidation state, (iii)used as semiconductor.

Answer»


Solution :(i) As a ELECTRONEGATIVITY of element decreases from C to Pb,the acidiccharacter of theirdioxide also decreases from C to Pb.THUS, C forms the most acidic dioxidei.e., `CO_(2)`.
(ii) Since theinert paireffect becomesmore and more predominant does the group, therefore, STABILITY of +2 oxidation state increasesdown the group. thus, lead is commonly found in +2 oxidation state.
(iii) Siliconand germanium are neithertoo electronegativenor too electrpositive. Therefore they act as metalloidsand hence BEHAVEAS semiconductors.


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