1.

Show that ground state energy of electron in hydrogen atom is equal to the first excited state energy of electron in He^(+) ion, assuming that their Rydberg's constants are equal

Answer»

SOLUTION :`E_(n) = - R_(H) (Z^(2))/(n^(2)) = - 13.60 (Z^(2))/(n^(2)) eV`
For H-atom in the ground state, `Z = 1, n =1, :. E_(1) = -13.60eV`
For `He^(+)` ion in the first EXCITED state, `Z = 2, n = 2, E_(2) = - 13.60 xx (2^(2))/(2^(2)) = - 13.6 eV`
HENCE, the desired result is proved.


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