1.

Show that the reaction CO+1//2O_2 to CO_2 at 300 K is spontaneous. The standard Gibbs free energies of formation of CO_2 and COare -394.4 and -137.2 "kJ mole"^(-1)respectively.

Answer»

Solution :`CO+1//2O_2 to CO_2`
`DeltaG_"(REACTION)"^0=sum G_(f"(products)")^0-sum G_(f"(reactants)")^0`
`DeltaG_"(reaction)"^0=[G_(CO_2)^0]-[G_(CO)^0+1/2G_(O_2)^0]`
`DeltaG_"(reaction)"^0`=-394.4+[137.2+0]
`DeltaG_"(reaction)"^0=-257.2 "kJ MOL"^(-1)`
`DeltaG_"(reaction)"` of a reaction at a given temperature is NEGATIVE hence the reaction is spontaneous


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