1.

Solid A "and" B are taken in a closed container at a certain temperature. These two solids decompose are following equilibria are established simultaneously A(s)hArrX(g)+Y(g) K_(P_(1)=250atm^(2) B(s)hArrY(g)+Z(g) K_(P_(2)=? If the total pressure developed over the solid mixture is 50 atm. Then the value of K_(P) for the 2^(nd) reaction

Answer»

`375`
`625`
`225`
`250`

Solution :`A(s)X+Y`
`alpha alpha+beta`
`B(s)hArrY+Z`
`beta+alpha beta`
`rArrK_(P_(1)=alpha(alpha+beta)`
`K_(P_2)=beta(alpha+beta)`
`P_(total)=(alpha+beta)+alpha+beta=2(alpha+beta)`
`RARR 2(alpha+beta)=50rArr alpha+beta=25`
`rArr 250=25alpha rArr alpha=10,beta=15`
`rArr K_(P_(2)=beta(alpha+beta)=15xx25=375`


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