1.

Stability of the species Li_(2), Li_(2)^(-) and Li_(2)^(+) increases in the order of :

Answer»

`Li_(2) lt Li_(2) lt Li_(2)^(+)`
`Li_(2) lt Li_(2)^(+) lt Li_(2)^(-)`
`Li_(2) lt Li_(2)^(+) lt Li_(2)`
`Li_(2) lt Li_(2)^(-) lt Li_(2)^(+)`

Solution :`Li_(2) sigma (1S)^(2) sigma^(**) (1s)^(2) sigma (2s)^(2)` ,
BOND ORDER ` = (1)/(2) (4-2) = 1 `
`Li_(2) ^(+) sigma (1s)^(2) sigma^(**) (1s)^(2) sigma (2s)^(1)` ,
Bond order`= (1)/(2) (3-2) = (1)/(2)`
`Li_(2)^(-) sigma (1s)^(2) sigma^(**) (1s)^(2) sigma (2s)^(2)(2s)^(1) `,
Bond order = `(1)/(2) (4-3) = (1)/(2)`
`LI_(2)^(-)` is less STABLE than ` Li_(2)^(+)` because ` Li_(2)^(-)` has more
number of electrons in the antibonding molecular
orbitals . Otherwisegreater the bond order , greater
is the stability . HENCE , the correct order is
`Li_(2)^(-) lt Li_(2)^(+) lt Li_(2) ` .


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