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State Raoult law and obtain expression forlowering of vapour pressure when nonvolatile solute is dissolved in solvent. |
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Answer» <P> Solution :Roult's LAW :This law states that " in the case of a solution of volatile liquids the partial vapour pressure of each component (A & B) of the solution is directly proportional to its mole fraction "` P_(A) alpha X_A` ` (P_(A) ^(@)" is the vapour pressure of pure component") ` when ` X_A=1 , ` then k =` p_(A)^(@) ` ` P_(B) =p_B^(@) ,X_b ` When a nonvolatile solute is dissolved in a pure water the VAPOURPRESSURE of the solution will depend only the solvent molecules as the solute in non-volatile ` P_("solute ") PROP X_A ` ` P_("solution ") = k,X_A ` ` X_A =1, k =P_("solvent ")^(@)-P_("solution ") ` Relativelowering of vapour pressure ` =("P_(solvent ") ^(@) -P_("solution ") )/( P_("solvent ") ^(@) ) =X_B ` where ` X_B ` =Mole fraction of the solute. |
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