1.

State Raoult law and obtain expression forlowering of vapour pressure when nonvolatile solute is dissolved in solvent.

Answer»

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Solution :Roult's LAW :This law states that " in the case of a solution of volatile liquids the partial vapour pressure of each component (A & B) of the solution is directly proportional to its mole fraction "
` P_(A) alpha X_A`
` (P_(A) ^(@)" is the vapour pressure of pure component") `
when ` X_A=1 , ` then k =` p_(A)^(@) `
` P_(B) =p_B^(@) ,X_b `
When a nonvolatile solute is dissolved in a pure water the VAPOURPRESSURE of the solution will depend only the solvent molecules as the solute in non-volatile
` P_("solute ") PROP X_A `
` P_("solution ") = k,X_A `
` X_A =1, k =P_("solvent ")^(@)-P_("solution ") `
Relativelowering of vapour pressure
` =("P_(solvent ") ^(@) -P_("solution ") )/( P_("solvent ") ^(@) ) =X_B `
where ` X_B ` =Mole fraction of the solute.


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