1.

State the Newland's law of octaves. (i) What are the two exceptions of block division in the periodic table?

Answer»

Solution :The Law of octaves states that, "when elements are arranged in the order of INCREASING atomic weights, the properties of the eighth ELEMENT are a REPETITION of the properties of thefirst element"
(ii) 1.Helium has two electrons. Its electronic configuration is `1s^(2)`?. As per the configuration, it is Supposed to be placed in .s. block, but actually placed in `18^(th)` group which belongs to .p. block. Because it has a completely filled valence shell as the other elements present in `18^(th)` group. It also resembles with `18^(th)` group elements in other properties. Hence helium is placed with other noble gases.
2. The other exception is hydrogen. It has only one s-electron and hence can be placed in group 1. It can also GAIN an electron to achieve a noble gas arrangement and hence it slovens `(17^(th))` group elements). Because of these assumptions, position of hydrogen becomes a special case. Finally, it is placed separately at the top of the periodic table.


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