1.

Statement-1. The pK_(a) of a weak acid becomes equal to pH of the solution at the mid-point of its titration. Statement-2. The molar concentrations of proton acceptor and proton donor become equal at mid point of a weak acid.

Answer»

Statement-1 is True, Statement-2 is True , Statement-2 is the CORRECT EXPLANATION of Statement - 1 .
Statement-1 is True, Statement - 2 is True , Statement-2 is NOT a correct explanation for Statement-1.
Statement-1 is True, Statement-2 is False.
Statement-1 is False, Statement-2 is True.

Solution :Statement-2 is the correct explanation of statement -1, because `pH = pK_(a) +log.(["Salt"])/(["Acid"])`.
At mid POIND, [Salt] = [Acid].


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