1.

Statuse and paintings coated with white lead turn black on long exposure to atmosphere. The original colour can be restored by treating them with H_(2)O_(2). The reason behind this is

Answer»

blackened statues get coated with PBS which on reaction with `H_(2)O_(2)` is oxidised to WHITE `PbSO_(4)`
`H_(2)O_(2)` DISSOLVES the COATING white lead and exposes the inner surface.
White lead reacts with `H_(2)O_(2)` to form white `PbSO_(4)`
blackened STATUSE get coated with lead sulphate which reacts with `H_(2)O_(2)` to give PbS.

Solution :The statues and paintings coated with white lead get blackened due to action of `H_(2)S` present in traces in atmosphere. When these are treated with `H_(2)O_(2)`, PbS is oxidised to `PbSO_(4)` which is colourless or white.
`underset("black")(PbS)+4H_(2)O_(2)to underset("white")(PbSO_(4))+4H_(2)O`


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