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Structures and IUPAC names of some hydrocarbons are given below. Explain why the names given in the parentheses are incorrect. (a) underset("2, 5,6-Trimethyloctane (and not 3,4,7-Trimethyloctane)")(CH_(3) - underset(underset(CH_(3))(|))(CH)- CH_(2) - CH_(2) - underset(underset(CH_(3))(|))(CH)-underset(underset(CH_(3))(|))(CH)-CH_(2) - CH_(3)) (b) underset("3-Ethyl-5-methylheptane (and not 5-Ethyl-3-methylheptane)")(CH_(3) - CH_(2) - underset(underset(CH_(2)CH_(3))(|))(CH)- CH_(2) - underset(underset(CH_(3))(|))(CH)- CH_(2) - CH_(3)) |
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Answer» Solution :(a) LOWEST locant number, 2, 5, 6 is lower than 3, 5, 7 (b) Substituents are in equivalent position, lower number is given to the one that comes FIRST in the name according to alphabetical order |
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