1.

The AsF_(3) molecule is trigonal bipyramidal. The hybrid orbitals used by the As atoms for bonding are-

Answer»

<P>`3_(x^(2)-y^(2)),d_(z^(2)),s,p_(x),p_(y)`
`d_(xy),s,p_(x),p_(y),p_(z)`
`d_(x^(2)-y^(2)),s,p_(x),p_(y)`
`s,p_(x),p_(y),p_(z),d_(z)^(2)`

Solution :`AsF_(5)` has `sp^(3)d` hybridisation. In `sp^(3)d` hybridisaton, the `d_(z^(2))` orbital is used along with the 's' and three 'p' orbitals to form three EQUATORIAL BONDS and two equally strong axial bonds for a trigonal BIPYRAMID.


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