1.

The bond dissociation energies of`X_(2),Y_(2)andXY` are in the ratio of`1:0.5:1.DeltaH` for the formation of `XY`is `-200kJmol^(-1)`.The bond dissociation energy of `X_(2)`will beA. `200KJmol^(-1)`B. `100KJmol^(-1)`C. `800KJmol^(-1)`D. `400 KJ mol^(-1)`

Answer» Correct Answer - A
Let `B.E.` of `x_(2),y_(2)` & `xy` are `xKJmol^(-1) , 0.5xKJmol^(-1)` and `xKJmol^(-1)` respectivaly
`(1)/(2)x_(2)+(1)/(2)y_(2)rarrxy,Delta=-200KJmol^(-1)`
`DeltaH=-200=Sigma(B.E)_("Reactant")=Sigma(B.E.)_("Product")`
`=(1)/(2)B.E_(x-x)+(1)/(2)B.E_(y-y)-B.E_(x-y)`
`=[(1)/(2)xx(x)+(1)/(2)xx(0.5x)]-[1xx(x)]`
`B.E.` of `x_(2)=x=800KJmol^(-1)` .


Discussion

No Comment Found

Related InterviewSolutions