1.

The bond dissociation energy depends upon the nature of the bond and nature of the molecule. If any molecule more than 1 bonds of similar nature are present then the bond energy reported is the average bond energy. If enthalpy of hydrogenation of C_(6)H_(6(l)) "into" C_(6)H_(12(l)) " is " -205 kJ and resonance energy of C_(6)H_(6(l)) is -152kJ//mol then enthalpy of hydrogenation of is ? Answer Delta H_("vap") " of " C_(6)H_(6(l)), C_(6)H_(10(l)), C_(6)H_(12(l)) all are equal:

Answer»

`-535.5` kJ/mol
`-238` kJ/mol
`-357` kJ/mol
`-119` kJ/mol

Solution :Heat of HYDROGENATION of cyclo HEXANE
`=("Heat of Hydrogenation of Benzene + Resonance ENERGY")/(3)`
`= (-205 + (-152))/(3) = -199kJ`


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