1.

The bond dissociation energy of B–F in `BF_​3` is 646 kJ `mol^(–1)` whereas that of C-F in `CF​_4` is 515 kJ `mol^(–1)`. The correct reason for higher B-F bond dissociation energy ascompared to that of C-F is:-A. Significant `ppi-ppi` interaction between B and F in `BF_​3` whereas there is no possibility of such interaction between C and F in `CF_​4`​.B. Lower degree of `ppi-ppi` interaction between B and F in `BF_3` than that between C and F in `CF_4`C. Smaller size of B atom as compared to that of C atomD. Stronger bond between B and F in `BF_3` as compared to that between C and F in CF

Answer» Correct Answer - A
In `BF_3 .ppi-ppi` back bonding is present .


Discussion

No Comment Found

Related InterviewSolutions