1.

The bond enthalpies of D-Dand O-O and D-O are respectively, + 440, +498 and + 491.5 kJ mol^(-1). Calculate DeltaH for the reaction D_(2(g)) + 1/2 O_(2(g)) to D_2O_((l))

Answer»

SOLUTION :Heat of reaction, `DeltaH `= (ENTHALPY of bonds dissoicated) - (Enthalpy of bonds FORMED)
`DeltaH = (440 + 498/2) - (2 xx 491.5)`
`= 689 - 983 = -294 kJ`
Enthalpy of the GIVEN reaction is -294 kJ.


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